What is Potassium Chlorate? — A Clear Guide (with supplier note: Potassium Chlorate Suppliers — E&M)
Potassium chlorate (chemical formula KClO₃) is a white crystalline inorganic salt best known as a strong oxidizer. It’s been used in laboratories and industry for well over a century because it readily gives up oxygen under the right conditions. That oxygen-releasing ability makes potassium chlorate useful — and also potentially hazardous — so anyone working with it should understand what it is, where it’s used, and how to handle it safely.
Basic properties
Chemical formula: KClO₃
Appearance: White crystalline solid (often granular or powder)
Molar mass: 122.55 g·mol⁻¹ (approx.)
Solubility: Moderately soluble in water (solubility increases with temperature); insoluble in many organic solvents
Behavior: Strong oxidizing agent; decomposes on heating to produce potassium chloride (KCl) and oxygen (O₂)
How it works (in simple terms)
As an oxidizer, potassium chlorate provides oxygen to other substances during chemical reactions. When heated sufficiently or contacted with certain reducing agents (especially organic materials, sulfur, or finely divided metals), it can accelerate combustion or even cause spontaneous ignition. That characteristic is why it’s useful in some controlled industrial roles — and why it must be stored and handled with care.
Common uses
Potassium chlorate has a range of historical and modern applications, many of which take advantage of its oxygen-donating ability:
Laboratory reagent: Used in certain qualitative and quantitative analyses as an oxidizing agent.
Industrial oxygen sources: Historically used in oxygen-generating mixtures (e.g., oxygen candles), though alternatives are often preferred today.
Matches and pyrotechnics (historical): It was widely used in match heads and some fireworks formulations because it supports rapid combustion. Due to safety concerns, many formulations have shifted to safer oxidizers.
Chemical manufacturing: Serves as an intermediate or reagent in producing other chemicals.
Disinfectants and bleaching (select applications): In controlled uses, it can assist in oxidative bleaching or disinfection, though safer oxidants are commonly used instead.
Note: Because of misuse risk, potassium chlorate’s role in pyrotechnics and explosives has been curtailed in many places and is often subject to regulation. If you need it for any application that might be sensitive, check local rules and industry best practices.
Safety and handling — what you must know
Potassium chlorate is not a benign substance. Key safety considerations:
- Strong oxidizer:Keep it away from organic materials, reducing agents, sulfur, phosphorus, and finely divided metals (e.g., aluminum, magnesium). Contact with these can cause fire or explosions.
- Avoid contamination:Even trace amounts of combustible contaminants can create dangerously reactive mixtures. Use clean tools and containers.
- Storage:Store in a cool, dry, well-ventilated area away from combustible materials and incompatible chemicals. Use tightly closed, labeled containers.
- Personal protective equipment (PPE):Gloves, eye protection, and lab coat are a minimum. For larger-scale handling, follow chemical hygiene plans and use appropriate respirators or engineering controls as required.
- Spill response and disposal:Don’t sweep up with combustible brooms or use combustible tools. Follow local hazardous-waste regulations for disposal; do not dispose of large quantities down drains or into the environment.
- Emergency:In case of fire involving potassium chlorate, standard extinguishing approaches that rely on smothering may be ineffective because the compound supplies oxygen. Use appropriate firefighting agents and notify emergency responders about the oxidizer hazard.
Because regulations and best practices vary by application and jurisdiction, always consult the Safety Data Sheet (SDS/MSDS) for the specific grade you purchase and follow local laws and workplace safety guidance.
Environmental and health aspects
Toxicity: Potassium chlorate can be harmful if swallowed and is an irritant to skin and eyes. Large exposures can be more serious due to oxidative effects on biological tissues.
Environmental concern: As an oxidizer and soluble salt, releases to waterways should be prevented; it can be harmful to aquatic life. Proper containment and disposal minimize these risks.
Alternatives and modern trends
In many applications where potassium chlorate was once common (e.g., matches, consumer pyrotechnics, certain bleaching processes), manufacturers have moved to safer, less reactive oxidizers or different technologies entirely. If you’re evaluating options for an industrial process, discuss alternatives and risk trade-offs with a technical supplier or chemist.
Choosing a supplier — what to look for
If your project or lab requires potassium chlorate, pick a supplier who provides:
- Clear product specifications(purity, particle size, form)
- Up-to-date Safety Data Sheets (SDS)and technical documentation
- Proper packaging and transportfor oxidizers
- Compliance with local shipping and regulatory requirements
- Technical support for safe handling and storage guidance
Potassium Chlorate Suppliers — E&M
If you’re searching for a dependable source, E&M offers a range of potassium chlorate products tailored for laboratory and industrial customers. E&M provides certified material specifications, accessible SDS documentation, and logistics support to ensure safe packaging and shipment of oxidizers. Whether you need a high-purity reagent for analytical work or bulk material for industrial processes, E&M can help match the right grade to your application while advising on handling and regulatory considerations.
For inquiries about product grades, certificates of analysis, or to request SDS and shipping details, contact Potassium Chlorate Suppliers — E&M directly. Make sure to explain your intended use so the supplier can recommend the safest and most suitable option.
Final notes
Potassium chlorate is a powerful chemical with useful roles in chemistry and industry — but with those capabilities come important safety and regulatory responsibilities. Use the correct grade, follow SDS guidance, keep it separated from incompatible materials, and work with reputable suppliers (like E&M) to ensure safe procurement and compliance.

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